I have encountered this shoe wear pattern before but I don't think it's connected to AS in any way. It's more likely to be the result of high arches or low muscle tone resulting in bodyweight being concentrated towards the outside edges of the feet. High arches is almost the opposite condition of flat feet. The tyre fitter makes valid points and appears to know more than the medical professionals do. I would not dismiss this advice as nonsense in future investigations.
My recommendation is that your son has an appointment with an independent
podiatrist. Most towns in England have at least one practice and they are advertised in Yellow Pages or on the internet. There is no requirement to have to go through your GP for a referral but you do have to pay for each appointment.